Analyzing the Fragmentation of COOD⁺

Vanessa Sanders, Kansas State University, Physics & Computer Engineering Major
Mentored by Dr. Itzik Ben-Itzhak

 

My project has involved gathering and analyzing data pertaining to the fragmentation of the molecular ion COOD⁺.

COOD⁺ Fragmentation

Fig. 1. COOD⁺ Fragmentation

An ion beam of this molecule is produced at a source, then fragmented using a laser, and the fragments are detected using two detectors.

Experimental Setup
Fig. 2. Experimental Setup

From this experiment, I determine which fragments are produced, as well as the ratio in which they are produced.

Time of Flight Graph of COOD⁺ Fragments

Fig. 3. Time of Flight Graph of COOD⁺ Fragments

Additionally, I compare these results when certain parameters are changed, namely the intensity and wavelength of the laser.

Branching Ratios for Different Intensities

Fig. 4. Branching Ratios for Different Intensities

I find that while changing the intensity does not impact the fragmentation of this ion, changing the wavelength alters fragmentation in several aspects, such as the kinetic energy released by the process.

Kinetic Energy Released for Different Wavelengths

Fig. 5. Kinetic Energy Released for Different Wavelengths

Alongside Samuel Diener, I also draw a comparison between COOD⁺ and HCO₂⁺​, shown here in branching ratios.

Branching Ratios for Different Ions

Fig. 6. Branching Ratios for Different Ions

This research provides a wealth of information about COOD⁺, including its relative bond strengths and the impact of changing conditions on its fragmentation. Overall, this provides key insight for a theoretical investigation of molecular structure, not only for this molecule, but for countless others that we could analyze moving forward.


Acknowledgments
Naoki Iwamoto, Nirmallya Das,​ Samuel Diener, Itzik Ben-Itzhak,​ James R. Macdonald Laboratory​. REU funded by the National Science Foundation, Award No. 2244539​. Experiment funded by the Department of Education. ​

Final Presentation